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Modelling Li-ion cell thermal runaway triggered by an internal short circuit device using an efficiency factor and Arrhenius formulations

机译:使用效率因子和Arrhenius公式对内部短路设备触发的锂离子电池热失控建模

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摘要

This paper presents a novel model for analyzing the thermal runaway in Li-ion battery cells with an internal short circuit device implanted in the cell. The model is constructed using Arrhenius formulations for representing the self-heating chemical reactions and the State of Charge. The model accounts for a local short-circuit, which is triggered by the device embedded in the cell windings (jelly roll). The short circuit is modeled by calculating the total available electrical energy and adding an efficiency factor for the conversion of electric energy into thermal energy. The efficiency factor also accounts for the energy vented from the cell. The results show good agreement with the experimental data for two cases – a 0D model and a 3D model of a single cell. Introducing the efficiency factor and simplifying the short-circuit modeling by using an Arrhenius formulation reduces the calculation time and the computational complexity, while providing relevant results about the temperature dynamics. It was found that for an 18650 NCA/graphite cell with a 2.4 Ah capacity, 28% of the electrical energy leaves with the effluent.
机译:本文提出了一种用于分析锂离子电池单元中植入内部短路装置的热失控模型。该模型使用Arrhenius公式构建,用于表示自热化学反应和荷电状态。该模型说明了局部短路,这是由嵌入单元绕组(果冻卷)中的设备触发的。通过计算总可用电能并添加将电能转换为热能的效率因子来对短路进行建模。效率因子还说明了从电池中排出的能量。结果显示与两种情况下的实验数据非常吻合-一个单元的0D模型和3D模型。通过使用Arrhenius公式引入效率因子并简化短路建模,可以减少计算时间和计算复杂度,同时提供有关温度动态的相关结果。已发现,对于容量为2.4 Ah的18650 NCA /石墨电池,废水中有28%的电能离开。

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